Product ID:GENETRON 12/114 MIXES
MSDS Date:04/01/1991
FSC:6830
NIIN:00N063062
MSDS Number: BYVML

ALLIED SIGNAL INC

MORRISTOWN, NJ 07962
US

Emergency Phone: 201-455-2000

Info Phone: 201-455-4157

Cage: 0LYW2

ALLIED-SIGNAL INC INDUSTRIAL FIBERS DIV

31 PETERSBURG, VA 23804 US

Telephone: 804-520-3321

Cage: 0LYW2

METHANE, DICHLORODIFLUORO-;(GENETRON 12) (SARA 313)

CAS: 75-71-8

RTECS: PA8200000

Fraction By Weight: 1.99%

OSHA PEL 1000 PPM

ACGIH TLV: 1000 PPM; 9495

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

ETHANE,1,2-DICHLORO-1,1,2,2-TERAFLUORO-;(GENETRON 114)(SARA

CAS: 76-14-2

RTECS: KI1101000

Fraction By Weight: 99-1%

OSHA PEL 1000 PPM

ACGIH TLV: 1000 PPM; 9495

SODIUM, POTASSIUM, CALCIUM. POWDERED

RTECS: 9999999ZZ

THESE ARE TOXIC AND CORROSIVE.

RTECS: 9999999ZZ

CAN CAUSE FROSTBITE, INDICATED BY

RTECS: 9999999ZZ

NO CHRONIC TOX

RTECS: 9999999ZZ

CFC'S, SUBSTANCES WHICH HARM PUBLIC HLTH & ENVIRON BY

RTECS: 9999999ZZ

THE OZONE LAYER CAN LEAD TO INCR ULTRAVIOLET RADIA

RTECS: 9999999ZZ

IN SKIN CANCER AND EYE CATARACTS.

RTECS: 9999999ZZ

BURNS FROM LIQ CONT. IF NO FROSTBITE, IMMED

RTECS: 9999999ZZ

CONTACT, LIFT EYELIDS OCCASIONALLY DURING WASHING TO

RTECS: 9999999ZZ

CYLINDER(S) TO OUTDOORS & SET UPRIGHT ANY

RTECS: 9999999ZZ

ALLOW TO DISSIPATE. DO NOT ALLOW UNPROTECTED

RTECS: 9999999ZZ

MATL. DISPOSAL BY A LICENSED WASTE DISPOSAL

RTECS: 9999999ZZ

KEEP VALVE TIGHTLY CLSD. NEVER DROP/REFILL

RTECS: 9999999ZZ

IF NOT HNDL PROPERLY. NEVER INTRODUCE FOREIGN

RTECS: 9999999ZZ

DANGEROUS. COMPLY W/OSHA REGS FOR COMPRESSED

RTECS: 9999999ZZ

BRTHG VAP & LIQ CONT W/EYES, SKIN & CLTHG. USE AUTH

RTECS: 9999999ZZ

HEAT. DO NOT DROP/PUNCTURE CYLS. FOLLOW STD SAFETY

RTECS: 9999999ZZ

VENT TO THE ATM. TO COMPLY WITH PROVISIONS OF THE

RTECS: 9999999ZZ

INFORMATION CAN BE FOUND IN

RTECS: 9999999ZZ

WHEREVER LEAKAGE IS PROBABLE. MECHANICAL (GENERAL)

RTECS: 9999999ZZ

OF MYLAR COATED DURAFAB(2ND

RTECS: 9999999ZZ

(ESPECIALLY FOR MIXES WITH BOILING POINTS 0F OR

RTECS: 9999999ZZ

WHERE CONTACT WITH LIQUID IS A REASONABLE

RTECS: 9999999ZZ

LD50 LC50 Mixture:SEE INGREDENTS.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:CHLOROFLUOROCARBON (CFC) MATERIALS
HAVE PRODUCED SENSITIZATION OF THE MYOCARDIUM TO EPINEPHRINE IN
LABORATORY ANIMALS & COULD HAVE A SIMILAR EFFECT IN HUMANS.
ADRENOMIMETICS (I.E., EPINEPHRINE) MAY BE CONTRA-INDICATED EXCEPT
FOR LIFE-SUSTAINING, USES IN HUMANS ACUTELY/CHRONICALLY EXPOS TO
CFCS .(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ:ACUTE:INHAL:OUTSIDE OF THE POSSIBILITY
OF ASPHY (WHEN OXYG LEVELS IN AIR ARE REDUCE TO 12-14%), THE CHIEF
SYMPS EXPECTED FROM THE MIX ARE CENTRAL NERVOUS SYSTEM (CNS)
DEPRESS & POSS NARCOTIC EFTS AT HIGH CONC LEVELS. INGEST:NOT
APPLIC, SINCE MATL IS GASEOUS AT NORMAL TEMP & PRESS. SKIN:CNTCT
W/LIQ MATL(ING 5)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:INGEST:CALL MD IMMED . INHAL:IMMED REMOVE TO FRESH AIR. IF
BRTHG HAS STOPPED, GIVE ARTF RESP, PREFERABLY MOUTH-TO-MOUTH. USE
OXYG AS REQ, PROVIDED A QUALIFIED OPERATOR IS AVAIL. DO NOT GIVE
EPIN EPHNNE (ADRENALINE). SKIN/EYE CNTCT:IMMED BATHE ANY FROSTBITE,
(DO NOT RUB) W/LUKEWARM (NOT HOT) H*2O. IN THE ABSENCE OF H*2O,
COVER W/SOFT WOOL/OTHER SUITABLE MATL. CNTCT MD FOR ANY
LOW-TEMP(ING 10)

Flash Point:NONFLAMMABLE
Extinguishing Media:ANY STANDARD AGENT-CHOOSE THE ONE THAT IS
APPROPRIATE FOR TYPE OF SURROUNDING FIRE. MATERIAL ITSELF IS
NONFLAMMABLE.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD PRESS DEMAND SCBA &
FULL PROT EQUIP . PROPER EYE & SKIN PROT SHOULD BE PROVIDED. USE
H*2O SPRAY TO KEEP FIRE-EXPOSED CNTNRS(SUPDAT)
Unusual Fire/Explosion Hazard:THERMAL DECOMP PRODS MAY INCLUDE
FLUORIDES, CHLORIDES & PHOSGENE. WHILE NOT COMBUST ITSELF, CNTCT
W/CERTAIN METALS MAY PRDCE EXOTHERMIC RXNS/(SUPDAT)

Spill Release Procedures:EVACUATE UNPROTECTED PERS FROM AREA. USING A
SELF-CONTAINED AIR SUPPLY & PROT AGAINST FROSTBT & EYE & SKIN
CNTCT, PERS INVOLVED W/CLEAN-UP SHOULD CLOSE ANY VALVES/REPAIR
SOUCE OF LEAK, REMOVE ANY OPEN FLAMES & PROVIDE VENT. REMOVE ANY
LEAKING(ING 12)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:STORE IN COOL, DRY, WELL-VENT AREA
(PREFERABLY OUTDOORS) AWAY FROM HEAT/DIRECT SUN. PROTECT CYLINDER &
ITS FITTINGS FROM PHYSICAL DAMAGE. (ING 15)
Other Precautions:NO SMOKING IN AREA OF USE. DO NOT USE IN THE GEN
VICIN OF ARC WELDING, OPEN FLAMES/HOT SURFS. HEAT AND/OR UV RADIA
MAY CAUSE THE FORMATION OF CHLORIDES, FLUORIDES/PHOSGENE . THESE
PRODS CAN CAUS E DEATH/SERIOUS PERSONAL INJURY (ING 16)

Respiratory Protection:NONE USUALLY REQ IN ADEQUATELY VENTILATED WORK
SITUATIONS. FOR ACCIDENTAL/NON-VENTILATED SITUATIONS, WERE CONCS
MAY BE HIGH, USE NIOSH/MSHA APPROVED SCBA/SUPPLIED AIR RESP W/FULL
FACEPIECE. FURTHER CH OICES & (ING 21)
Ventilation:VENT SHOULD BE ADEQ TO MEET TLV REQUIREMENTS & TO MINIMIZE
EXPOS. PROVIDE LOCAL EXHST AT FILLING ZONES & (ING 22)
Protective Gloves:IMPERVIOUS GLOVES W/OUTER LAYER(ING 23)
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS .
Other Protective Equipment:ANSI APPRVD EMER EYE WASH & DELUGE SHOWER .
ADD IMPERVIOUS BOOTS & CLTHG W/SIMILAR INSULATING LINING (ING 25)
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
SPEC GRAV:1.32-1.47 @ 21.1C (LIQ) (H*2O =1). VP:12.9-70.2 PSIG @ 21.1C.
VAP DENS:2.8-4.3 & 20C. PH:NOT DETERM BUT BELIEVED TO BE NEUTRAL.
FIRE FIGHT PROC:COOL, TO DISPERSE GAS/VAPS & TO PROTECT THOSE
ATTEMPTING TO STOP ANY LEAK. EXPO HAZ:POTENTIALLY EXPLOS
COMBINATION. SEE ALSO TOX DECOMP PRODS UNDER SECTION 5.

Boiling Pt:B.P. Text:>-21F,>-30C
Melt/Freeze Pt:M.P/F.P Text:>-252F,>-15
Vapor Pres:SUPDAT
Vapor Density:SUPDAT
Spec Gravity:SUPDAT
pH:SUPDAT
Evaporation Rate & Reference:<1 (ETHER = 1)
Solubility in Water:0.008-0.01 (% BY WT)
Appearance and Odor:COLORLESS, LIQUEFIED GAS, PRACTICALLY ODORLESS.
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
FRESHLY ABRADED ALUMINUM SURFS:CAUSE STRONG EXOTHERMIC
RXN-REFERENCE(S), CHEMICALLY-ACTIVE METALS, SUCH AS (ING 3)
Stability Condition to Avoid:HIGH TEMPS, LIGHTED CIGARETTES, HOT SPOTS,
WELDING. THESE CONDITIONS CAUSE DECOMPOSITION TO FORM TOXIC,
CORROSIVE GASES.
Hazardous Decomposition Products:CHLORIDES & FLUORIDES . HALOGENS,
HALOGEN ACIDS & POSSIBLY CARBONYL HALIDES, SUCH AS PHOSGENE.
(SUPDAT)

Waste Disposal Methods:DISP OF GENETRON 12/114 MIXES MAY BE SUBJECT TO
FED, STATE & LOCAL REGS. USERS SHOULD REVIEW THEIR OPERATIONS IN
TERMS OF APPLIC FED, STATE & LOCAL LAWS & REGS, THEN CONSULT
W/APPROP REGULATORY AGENCI ES BEFORE DISCHARGING/DISPOSING OF WASTE
(ING 14)

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.